‏845.00 ₪

Molecular Technology - Synthesis Innovation

‏845.00 ₪

ISBN13

9783527345885

יצא לאור ב

Weinheim

זמן אספקה

21 ימי עסקים

עמודים

432

פורמט

Hardback

תאריך יציאה לאור

17 באפר׳ 2019

לדלג לסוף של גלריית תמונות

לדלג להתחלה של גלריית תמונות

פרטים

Edited by foremost leaders in chemical research together with a number of distinguished international authors, this fourth volume summarizes the most important and promising recent developments in synthesis, polymer chemistry and supramolecular chemisty. Interdisciplinary and application-oriented, this ready reference focuses on innovative methods, covering new developments in catalysis, synthesis, polymers and more. Edited by foremost leaders in chemical research together with a number of distinguished international authors, this fourth volume summarizes the most important and promising recent developments in synthesis, polymer chemistry and supramolecular chemisty. Interdisciplinary and application-oriented, this ready reference focuses on innovative methods, covering new developments in catalysis, synthesis, polymers and more.

מידע נוסף

מידע נוסף
עמודים	432
פורמט	Hardback
ISBN10	3527345884
יצא לאור ב	Weinheim
תאריך יציאה לאור	17 באפר׳ 2019
תוכן עניינים	1 Polymerization-Induced Self-assembly of Block Copolymer Nano-objects via Green RAFT Polymerization 1 Shinji Sugihara 1.1 Introduction 1 1.2 Block Copolymer Solution 1 1.3 Synthesis of Block Copolymers via RAFT Polymerization 4 1.4 Polymerization-Induced Self-assembly 6 1.4.1 PISA Using RAFT Process: Emulsion and Aqueous Dispersion Polymerization 6 1.4.2 Reagents for RAFT Aqueous Dispersion Polymerization 9 1.4.2.1 RAFT Agents 9 1.4.2.2 Steric Stabilizer (Macro-CTA, Shell) 9 1.4.2.3 Monomers (Core) 9 1.4.3 Representative RAFT Aqueous Dispersion Polymerization 11 1.5 Promising Polymerization Technology 17 References 21 2 Chemical Functionalization of Graphitic Nanocarbons 31 Yuta Nishina 2.1 Purpose of Functionalization 31 2.2 Edge Functionalization 34 2.3 Basal Plane Functionalization 37 2.3.1 Hydrogenation and Halogenation 37 2.3.2 Radical Addition 37 2.3.3 Cycloaddition 40 2.4 Miscellaneous 42 2.4.1 Oxidation 42 2.4.2 Covalent Bond Formation via Halogenation 42 2.4.3 Rearrangement 42 2.5 Non-covalent Functionalization 44 2.5.1 Functionalization with - Interactions 45 2.5.2 Functionalization with van der Waals, Ionic Interactions, and Hydrogen Bonding 45 2.5.3 Functionalization with Polymers 46 2.6 Future Perspective of Graphitic Nanocarbon Functionalization 48 References 48 3 Synthetic Methods Using Interactions Between Sustainable Iron Reagents and Functionalized Carbon-Carbon Multiple Bonds 51 Takeshi Hata 3.1 Cross-coupling Reactions 52 3.1.1 C(sp2)-X/C(sp3)-Metal 52 3.1.2 C(sp2)-X/C(sp2)-Metal 54 3.1.3 C(sp2)-X/C(sp)-Metal 55 3.1.4 C(sp)-X/C(sp2)-Metal 55 3.1.5 C(sp3)-X/C(sp2)-Metal 55 3.1.6 Mizoroki-Heck Reaction 56 3.2 Substitution Reactions 56 3.3 Carbometallation 58 3.4 Conjugate Addition 59 3.5 Cycloaddition 67 3.5.1 [2+2] Cycloadditions 67 3.5.2 [3+2] Cycloadditions 68 3.5.3 [4+1] Cycloadditions 68 3.5.4 [4+2] Cycloadditions 68 3.5.5 1,3-Dipolar Cycloadditions 70 3.6 Others 71 3.6.1 C-H Bond Activation 71 3.6.2 Nazarov Cyclization 72 3.6.3 Friedel-Crafts Reaction 72 3.7 Conclusion 73 References 73 4 Molecular Technology for Switch and Amplification of Chirality in Asymmetric Catalysis Using a Helically Dynamic Macromolecular Scaffold as a Source of Chirality 77 Michinori Suginome 4.1 Introduction 77 4.2 Molecular Design and Synthesis of PQX-Based Chiral Catalysts 79 4.3 Dynamic, Bidirectional Induction of Helical Chirality to PQX 81 4.4 PQX as Chirality-Switchable Chiral Catalysts in Catalytic Asymmetric Synthesis 82 4.4.1 Palladium-Catalyzed Asymmetric Reactions Using PQXphos Bearing Monophosphine Pendants on PQX 82 4.4.2 Copper-Catalyzed Asymmetric Reactions Using PQXbpy Bearing 2,2'-Bipyridin-6-yl Pendants on PQX 87 4.4.3 Organocatalytic Asymmetric Reactions Using PQXap Bearing 4-Aminopyridin-3-yl Pendants on PQX 88 4.5 Chirality Amplification in Asymmetric Catalysis 90 4.6 Closing Remarks 92 References 92 5 Cooperative Double Activation Metal/Metal and Metal/Organic Catalysis Enabling Challenging Organic Reactions 95 Yoshiaki Nakao 5.1 Introduction 95 5.2 C-H Functionalization by Cooperative Double Activation Catalysis 96 5.3 C-C Functionalization by Cooperative Double Activation Catalysis 106 5.4 Miscellaneous Reactions by Cooperative Double Activation Catalysis 109 5.5 Summary and Outlook 113 References 114 6 Siloxane-Based Building Blocks forMolecular Technology 119 Shohei Saito, Naoto Sato, Masashi Yoshikawa, Atsushi Shimojima, and Kazuyuki Kuroda 6.1 Introduction 119 6.2 Siloxane Bond Formation for Organization 120 6.2.1 Hydrolytic Reactions 120 6.2.2 Non-hydrolytic Reactions 121 6.3 Various Organosilane and Siloxane-Based Building Blocks 123 6.3.1 Organosilanes 123 6.3.2 Cyclic Siloxanes 126 6.3.3 Cage Siloxanes 127 6.3.4 Branched and Dendritic Siloxanes 131 6.4 Structure and Morphology of Assembled Building Blocks 133 6.4.1 Organization of Building Blocks 133 6.4.2 One-Dimensionally Structured Materials 134 6.4.3 Two-Dimensionally Structured Materials 137 6.4.4 Three-Dimensionally Structured Materials 144 6.5 Conclusions 150 References 151 7 Organic Molecular Catalysts in Radical Chemistry: Challenges Toward Selective Transformations 163 Daisuke Uraguchi, Kohsuke Ohmatsu, and Takashi Ooi 7.1 Background 163 7.2 Organic Photocatalysts 169 7.3 Selective Transformations Catalyzed or Mediated by Organic Molecular Radicals 181 7.4 Radical Reactions Combined with Asymmetric Organic Molecular Catalysis 184 7.5 Future Outlook 192 References 192 8 Coordination Molecular Technology 199 Nobuto Yoshinari and Takumi Konno 8.1 Introduction: Coordination Molecular Technology 199 8.2 Non-Coulombic Ionic Solid (NCIS) 200 8.3 Low-Packing Type NCIS 201 8.3.1 Porous Materials 201 8.3.2 Classical Molecular Design of Porous Ionic Solids 203 8.3.2.1 "Giant Ion Approach" for Porous Ionic Solids 205 8.3.2.2 "Low Coordination Number Approach" for Porous Ionic Solids 206 8.3.3 Prototype of Porous Low-Packing Type NCIS 207 8.3.4 pH-Controlled Formation of Porous Low-Packing Type NCIS 209 8.3.5 Short Summary of Low-Packing Type NCIS 211 8.4 Ion-Fluid Type NCIS 211 8.4.1 Ion-Conducting Ionic Solids 211 8.4.2 MOF-Based Ion-Conducting Materials 213 8.4.3 Design of Ion-Conducting Materials Based on Metal-Organic Clusters 214 8.4.4 Prototype of Ion-Fluid Type NCIS 215 8.4.5 Ion-Exchange Ability of Ion-Fluid Type NCIS 217 8.4.6 Short Summary of Ion-Fluid Type NCIS 218 8.5 Charge-Separation Type NCIS 218 8.5.1 Ionic Crystals with Non-alternate Arrangement of Cations and Anions 219 8.5.2 Prototype of Charge-Separation Type NCIS 220 8.5.3 Functionality of Charge-Separation Type NCIS 224 8.5.3.1 Catalase-Like Activity 224 8.5.3.2 Negative Electrostrictive Effect 225 8.5.4 Short Summary of Charge-Separation Type NCIS 226 8.6 Conclusion 226 References 227 9 Molecular Technology for Synthesis of Versatile Copolymers via Multiple Polymerization Mechanisms 231 Kotaro Satoh 9.1 Introduction 231 9.2 Transformation of Active Species in Chain-Growth Vinyl Polymerization 234 9.2.1 Controlled/Living Polymerization of Vinyl Monomers 234 9.2.2 Indirect Transformation Involving Terminal Conversion and Tandem Polymerization 236 9.2.3 Umpolung One-Pot Direct Polymerization 238 9.3 Mechanistic Transformation Through Carbon-Halogen Bond 238 9.3.1 Transformation of Anionic or Coordination Polymerization 238 9.3.2 Combination of Radical and Cationic Polymerizations 242 9.4 Mechanistic Transformation Through Carbon-Sulfur Bond 243 9.4.1 Transformation Using RAFT Polymerization 243 9.4.2 Reversible Umpolung Transformation During Polymerization 244 9.5 Combination Between Step- and Chain-Growth Polymerization 248 9.5.1 Indirect Transformation for Block Copolymer Synthesis 248 9.5.2 Simultaneous Step- and Chain-Growth Polymerization 250 9.6 Conclusion 251 References 251 10 Self-assembled Monolayers from Carbon-Based Ligands on Metal Surfaces 259 Christene A. Smith and Cathleen M. Crudden 10.1 Introduction 259 10.2 NHC Ligands on Two-Dimensional Surfaces 260 10.3 NHCs on Three-Dimensional Surfaces 272 10.3.1 NHC-Stabilized Au Metal Nanoparticles 273 10.3.1.1 NHC-Stabilized Au Metal Nanoparticles by Ligand Exchange 273 10.3.1.2 NHC-Stabilized Au Metal Nanoparticles by Bottom-Up Methods 275 10.3.1.3 NHC-Stabilized Au Metal Nanoparticles from Ionic Liquids 277 10.3.1.4 Water-Soluble NHC-Stabilized Au Nanoparticle Syntheses 278 10.3.2 NHC-Stabilized Au Metal Nanoparticles 280 10.3.2.1 NHC-Stabilized Reactive Metal Nanoparticles: Iridium 282 10.3.2.2 NHC-Stabilized Reactive Metal Nanoparticles: Ruthenium 282 10.3.2.3 NHC-Stabilized Reactive Metal Nanoparticles: Palladium 284 10.3.2.4 NHC-Stabilized Reactive Metal Nanoparticles: Platinum 287 10.3.2.5 NHC-Stabilized Reactive Metal Nanoparticles: Silver 287 10.4 Conclusions and Outlook 288 References 289 11 Supramolecular Web and Application for Chiroptical Functionalization of Polymer 297 Hirotaka Ihara, Makoto Takafuji, Yutaka Kuwahara, Yutaka Okazaki, Naoya Ryu, Takashi Sagawa, and Reiko Oda 11.1 Introduction 297 11.2 Supramolecular Gel for Molecular Web 298 11.2.1 What is Supramolecular Gel? 298 11.2.2 Low Molecular Weight Tool for Supramolecular Gel Formation 299 11.3 Chiroptical Properties of Glutamide-Based Supramolecular Gel 305 11.3.1 Colorless and Transparent Property 305 11.3.2 Fluorescent Property 306 11.3.3 Phosphorescent Property 308 11.3.4 Induction of Secondary Chirality 310 11.3.5 Induction of Circularly Polarized Luminescence 311 11.4 Functionalization of Polymer with Supramolecular Web 319 11.4.1 Polymerizing Supramolecular Gel 319 11.4.2 Introduction of Supramolecular Gel Function in the Polymer 321 11.4.2.1 Introduction Through Bulk Polymerization 321 11.4.2.2 Introduction of Supramolecular Web into Polymer Through Blend Method 322 11.4.3 Development of Optical Modulator 324 11.4.3.1 Wavelength Converter by High Storks Shift and Phosphorescence 324 11.4.3.2 Circularly Polarized Luminescent Material 328 11.5 Conclusions 329 References 330 12 Conformational Analysis of Organic Molecules with Single-Molecule Atomic-Resolution Real-Time Transmission Electron Microscopy (SMART-TEM) Imaging 339 Koji Harano and Eiichi Nakamura 12.1 Introduction 339 12.2 Conformational Analysis 340 12.2.1 Conformational Analysis of Single Molecules 342 12.2.2 Alkyl Chain Passing Through a Hole 346 12.2.3 Bond-by-Bond Analysis of the Conformation of a Perfluoroalkyl Chain 346 12.2.4 Determination of the Conformation of the PF Chain of 6 347 12.2.5 Orientation of Single Molecules of 1 in a CNT 350 12.2.6 3-D Structural Information on the Pyrene Amide Molecule 352 12.3 Images of Moving Biotin Triamide in a Vacuum 352 12.4 Control of Molecular Motions by the Acceleration Voltage 354 12.5 A More Complex Biotin Derivative 356 12.6 Cross-correlation Between Experimental and Simulated TEM Images 358 12.6.1 Stability of Single Molecules Under SMART-TEM Observation 361 12.7 Conclusion 364 Appendix 12.A Procedures for SMART-TEM Experiments 365 12.A.1 Synthesis of Biotinylated CNH 10 365 12.A.2 Sample Preparation for TEM Observation of CNH 11 366 12.A.3 Procedure for TEM Observation in Figure L.8 366 12.A.4 Cross-correlation Analysis of Overall Motion of Single Organic Molecules in TEM Movies 366 References 367 13 Designer Molecules Toward Sequence-Controlled Polymers via Chain-Growth Propagation Mechanism 369 Makoto Ouchi 13.1 Introduction 369 13.2 Cyclopolymerization 371 13.3 Iterative Single Unit Monomer Addition by Transformable Bulkiness 373 13.4 Iterative Cyclization 374 13.5 Conclusion 376 References 377 14 Hairy Particles Synthesized by Surface-Initiated Living Radical Polymerization 379 Kohji Ohno 14.1 Introduction 379 14.2 Surface-Initiated Living Radical Polymerization on the Surfaces of Various Particles 380 14.3 Precise Synthesis of Polymer-Brush-Decorated Particles 382 14.3.1 Monodisperse Hybrid Particles 382 14.3.2 Janus Particles Grafted with Polymer Brush 383 14.3.3 Polymer-Brush-Grafted Hollow Particles 385 14.3.4 Mixed Polymer Brushes on Particles 386 14.4 Structure of Polymer Brushes on the Particle Surface 387 14.5 Self-assembly of Hairy Particles 388 14.5.1 Two- and Three-Dimensional Ordered Arrays 388 14.5.2 Advantages of Semisoft Colloidal Crystals 391 14.5.3 Self-assembly of Hairy Anisotropic Particles 392 14.6 Conclusions 393 References 393 Index 399
זמן אספקה	21 ימי עסקים